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Creators/Authors contains: "Raju, Cijil"

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  1. ; ; (, Chemical Science)
    Building on recent advancements, this perspective article examines key design principles that facilitate the use of reversible solid-state cycloaddition reactions for molecular solar thermal energy storage applications. 
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  2. ; ; ; ; ; ; ; ; (, Journal of Materials Chemistry A)
    A mechanistic investigation of molecular solar thermal energy release by solid-state cycloreversion of dianthracenes to anthracenes reveals the integral roles of chemical and physical transformations of molecules towards the total energy release. 
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  3. ; ; ; ; ; (, Communications Materials)
    Abstract Conventional topochemical photopolymerization reactions occur exclusively in precisely-engineered photoactive crystalline states, which often produces high-insoluble polymers. To mitigate this, here, we report the mechanoactivation of photostable styryldipyrylium-based monomers, which results in their amorphization-enabled solid-state photopolymerization and produces soluble and processable amorphous polymers. A combination of solid-state nuclear magnetic resonance, X-ray diffraction, and absorption/fluorescence spectroscopy reveals the crucial role of a mechanically-disordered monomer phase in yielding polymers via photo-induced [2 + 2] cycloaddition reaction. Hence, mechanoactivation and amorphization can expand the scope of topochemical polymerization conditions to open up opportunities for generating polymers that are otherwise difficult to synthesize and analyze. 
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  4. ; ; ; ; ; ; ; ; ; ; et al (, Chem)
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